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CH 3CH 2CO Cl is propanoyl chloride (or propionyl chloride). Acid Halides: The acyl group is named first, followed by the halogen name as a separate word.Į.g. A Greek letter identifies the location of the alkyl oxygen relative to the carboxyl carbonyl group. CH 3(CH 2) 2CO 2 C 2H 5 is ethyl butanoate (or ethyl butyrate).Ĭyclic esters are called lactones. Esters: The alkyl group is named first, followed by a derived name for the acyl group, the oic or ic suffix in the acid name is replaced by ate.Į.g. In the following examples the IUPAC names are color coded, and common names are given in parentheses. These are often used in common names of compounds. Three examples of acyl groups having specific names were noted earlier. Indeed, if hydrogen bonding is not present, the boiling points of comparable sized compounds correlate reasonably well with their dipole moments. The relatively high boiling points of equivalent 3º-amides and nitriles are probably due to the high polarity of these functions. The last nine entries in the above table cannot function as hydrogen bond donors, so hydrogen bonded dimers and aggregates are not possible. Physical Properties of Some Carboxylic Acid Derivatives Similar hydrogen bonding occurs between molecules of 1º and 2º-amides (amides having at least one N–H bond), and the first three compounds in the table serve as hydrogen bonding examples. As noted earlier, the relatively high boiling point of carboxylic acids is due to extensive hydrogen bonded dimerization. Boiling points are given for 760 torr (atmospheric pressure), and those listed as a range are estimated from values obtained at lower pressures. An aldehyde and ketone of equivalent molecular weight are also listed for comparison. The following table lists some representative derivatives and their boiling points. Some examples of these functional derivatives were displayed earlier. Carboxylic acids have a hydroxyl group bonded to an acyl group, and their functional derivatives are prepared by replacement of the hydroxyl group with substituents, such as halo, alkoxyl, amino and acyloxy. If these same functional groups are attached to an acyl group (RCO–) their properties are substantially changed, and they are designated as carboxylic acid derivatives. The important classes of organic compounds known as alcohols, phenols, ethers, amines and halides consist of alkyl and/or aryl groups bonded to hydroxyl, alkoxyl, amino and halo substituents respectively. An interesting feature is the Power View where you can chat with up to 4 people simultaneously. Just like Pushbullet and AirDroid, you can send links and text to your phone from the computer. They have added support for backing up photos and videos. You can view and dismiss all notifications on your computer but can’t interact with it.Īlso Read: 10 Best Notification Apps for Android (2018) One cool feature is the ability to schedule messages but many SMS apps now offer that function. You can view, manage, and send text messages remotely. That doesn’t mean that’s the only thing it is good at. Platform: Windows, macOS, Android, iOS, Web, Chrome ExtensionĪs the name suggests, MightyText is more about messaging than anything else. For $2.99, you get remote camera access, local file transfer, remove ads, 1GB file transfer, and unlimited data transfer.ĭownload AirDroid (Freemium, $2.99) 2. AirDroid free has 30MB file transfer and 200MB data transfer limit. AirDroid also offers a web client so you can use it without installing a native client. Maximize the window on your computer and you have ads and lag-free screen mirroring.Īll mobile notifications will be mirrored on the big screen and you will be able to interact with it. You can click on the Screenshot icon and it’ll bring up the phone’s display. Another hidden feature of Airdroid is screen mirroring. Transferring files is as easy as dragging and dropping them. You can also access the camera and start recording if you want. While Pushbullet focuses more on mirroring notification, AirDroid strength lies in transferring data between Computer and Android.ĪirDroid will connect with your Windows or macOS computer, allowing you to control it remotely. Platform: Windows, macOS, Android, iOS, WebĪirDroid is probably one of the best Pushbullet alternatives with a comparable feature set and a lower price point. In case you don’t want to pay for the Pushbullet subscription, here are 8 Pushbullet alternatives that can provide all these features for free. For instance, file sending is limited to 25 Mb between devices. But ever since Pushbullet switched to a subscription model ($4.99 per month), they took away a lot of features from the free one. Sharing files and snippets of text or links is super easy. You can instantly receive notifications from your smartphone to your laptop and interact with it. Pushbullet is probably the gold standard of cross-platform notification and file sync technology. She does not appear in the show until "My Sister from Another Mother. Her name stands for "Junior Undercover Digital Youth". Her robotic nature makes her very smart, but she has no social skills, although she is considered to be sassy. and Ernie's sarcastic robot sister who looks like a 10-year-old girl. He is often ignored by his parents, especially his father, who treats him as expendable during missions, which gives him a severe inferiority complex. He is a computer genius and joins the family's spy team in " My Sister From Another Mother. and Judy's brother and a stereotypical nerd. In " Photo Bombed", she learns about K.C.'s spy life. She is cheerful, girly and a very outgoing person. Veronica Dunne as Marisa Clark, K.C.'s best friend.Granddaughter to Gayle King and Othello King. She is the daughter of Kira and Craig Cooper. She is a member of a government spy organization. She is highly proficient at math and karate. Cooper, a high school student by day and an undercover spy whenever. and her family as they contend with common familial issues while also performing missions to save the country, with a recurring storyline involving thwarting the plans of a criminal organization.Ĭast and characters Main Her brother tries to help because he feels left out and eventually joins the team, and his desire leads his mother and father to get a new robot child. Cooper, a high school math genius, who gets recruited by her parents after she discovers that they are secretly undercover spies working for an agency called The Organization. Set in Washington, D.C., the series follows K.C. The series stars Zendaya, Veronica Dunne, Kamil McFadden, Trinitee Stokes, Tammy Townsend, and Kadeem Hardison. Undercover is an American comedy television series created by Corinne Marshall that aired on Disney Channel from Januto February 2, 2018. Under Construction, Second Chances, Revenge of the Van People, K.C.K.C.
It was to this very theatre he returned in 1961 when he sought to create his own surreal theatre and museum space. Dali’s Theatre-Museum was opened to the public in 1974.ĭali’s eccentric style exudes from every surface of this building. It feels like the space is performing rather than just displaying art. We love the way he designed this experience with his audience in mind. His drawings, paintings, frescos and furniture are all actors on a stage – around which we move. It is a very personal and interactive experience where you feel the artist is still present. Also within the museum since 1999 is the collection of jewels with accompanying drawings and specifications by the artist.ĭali even included his car – with surreal tear-like additions – in the space. Dali spent his final days in the Torre Galatea section of the museum and was buried here in the crypt. The town of Figueres is located between Barcelona and the French border. It is accessible by rail from Barcelona (just 53 mins) and by overnight train from Paris. When walking about the town – don’t miss The Face of Dali at the end of the Rambla– a tribute by the city to its most famous resident in 1961. The Torre Galatea at the Dalí Museum-Theatre in Figueres Catalonia. Photo credit: papalars via photopin ccĪs a child, Dali spent his summers with his family at Cadaques – a picturesque whitewashed fishing village 35km east of Figueres. Dali often painted at this house and his parents built him a studio there and even organised an exhibition of his work after his first year of art school – in the house. When Dali moved to Madrid and Paris he often invited friends such as Fernando Federico Lorca, Luis Buñuel and Reny Magritte to holiday with him in Cadaques. It was the place he was first photographed upon his return in 1948 to Spain following the Spanish Civil War. Today, Cadaques is a full of restaurants, craft shops and galleries and is a very pleasant place to spend a day or two. Just one kilometre away from the bustling port is Dali’s House at Portlligat. Its bays and inlets offer a beautiful backdrop for one of the most special residences in Spain. The house – open to the public – is full of personality, charm and wit. We love the studio where Dali worked, the large egg on a rooftop, his wife, manager and muse Gala’s round room and of course, the pink lips and other sculptures in the garden.Ĭadaques and Portlligat are best reached by car from Figueres. And if you have the time – you can explore nearby Cap de Creus. The cape’s unusual rock formations feature in a number of Dali’s works such as The Persistence of Memory. The cape was declared a national park in 1998. The garden at Pubol Castle – Gala’s haven in Catalonia. Photo credit: El próximo viaje / Victoriamdq via photopin ccĪs a child, Dali was a frequent visitor to the Catalonia capital and was struck by the modernism of UNESCO-listed architect Gaudi’s work. In an interview with Revista magazine in 1953, Dali spoke about Park Güell and the need to fund-raise for Gaudi’s as yet unfinished La Sagrada Familia (it’s still unfinished!). In 1956, Dali gave a talk at the Park in honour of the architect. He also loved Gaudi’s La Pedrera building and cites it in French publication in 1930 and in 1952 was photographed there for a Spanish publication. Elsewhere in the city there are many galleries, museums and theatres where Dali exhibited and spoke that are still open to the public – for example the Salas Pares where he frequently exhibited at the beginning of his career the Teatro Goya where he designed set for a play in 1927 – for his friend Lorca. And the Ateneu – where he spoke at a conference in 1950. Unfortunately many of the restaurants and bars Dali frequented have closed or deteriorated significantly.NOTE: As of Decemthe most recent Ubuntu 16.04 kernel 4.4.0-53 performs extremely well and better than 4.8.4 in most circumstances. |
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